LeHavreV1, Main, Exploration, bibRecord, 001452

First C3v-symmetrical calix[6](aza)crown.

Identifieur interne : 001452 ( Main/Exploration ); précédent : 001451; suivant : 001453

First C3v-symmetrical calix[6](aza)crown.

Auteurs : Ivan Jabin [France] ; Olivia Reinaud

Source :

The Journal of organic chemistry [ 0022-3263 ] ; 2003.

RBID : pubmed:12713340

Abstract

The first C(3v)-symmetrical calix[6](aza)crown 8 has been obtained in five steps from X(6)H(3)Me(3) 3. The key-step introduction of the triple bridge at the small rim has been achieved through reaction of a tris-arylsulfonamide derivative of tren 1 and tris-tosylcalix[6]arene 6. A (1)H NMR study has shown that the tripodal cap rigidifies the whole edifice, preventing ring inversion and constraining the calixarene core in a straight cone conformation.

DOI: 10.1021/jo026642h
PubMed: 12713340

Affiliations:

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">First C3v-symmetrical calix[6](aza)crown.</title>
<author><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name>
<affiliation wicri:level="4"><nlm:affiliation>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex, France. ivan.jabin@univ-lehavre.fr</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Région Normandie</region>
<region type="old region" nuts="2">Haute-Normandie</region>
<settlement type="city">Le Havre</settlement>
</placeName>
<orgName type="university">Université du Havre</orgName>
</affiliation>
</author>
<author><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PubMed</idno>
<date when="2003">2003</date>
<idno type="RBID">pubmed:12713340</idno>
<idno type="pmid">12713340</idno>
<idno type="doi">10.1021/jo026642h</idno>
<idno type="wicri:Area/PubMed/Corpus">000342</idno>
<idno type="wicri:Area/PubMed/Curation">000342</idno>
<idno type="wicri:Area/PubMed/Checkpoint">000342</idno>
<idno type="wicri:Area/Ncbi/Merge">000067</idno>
<idno type="wicri:Area/Ncbi/Curation">000067</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000067</idno>
<idno type="wicri:doubleKey">0022-3263:2003:Jabin I:first:c:v</idno>
<idno type="wicri:Area/Main/Merge">001487</idno>
<idno type="wicri:Area/Main/Curation">001452</idno>
<idno type="wicri:Area/Main/Exploration">001452</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en">First C3v-symmetrical calix[6](aza)crown.</title>
<author><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name>
<affiliation wicri:level="4"><nlm:affiliation>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex, France. ivan.jabin@univ-lehavre.fr</nlm:affiliation>
<country xml:lang="fr">France</country>
<wicri:regionArea>URCOM, Université du Havre, Faculté des Sciences et Techniques, 25 rue Philippe Lebon, BP 540, 76058 Le Havre Cedex</wicri:regionArea>
<placeName><region type="region" nuts="2">Région Normandie</region>
<region type="old region" nuts="2">Haute-Normandie</region>
<settlement type="city">Le Havre</settlement>
</placeName>
<orgName type="university">Université du Havre</orgName>
</affiliation>
</author>
<author><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name>
</author>
</analytic>
<series><title level="j">The Journal of organic chemistry</title>
<idno type="ISSN">0022-3263</idno>
<imprint><date when="2003" type="published">2003</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The first C(3v)-symmetrical calix[6](aza)crown 8 has been obtained in five steps from X(6)H(3)Me(3) 3. The key-step introduction of the triple bridge at the small rim has been achieved through reaction of a tris-arylsulfonamide derivative of tren 1 and tris-tosylcalix[6]arene 6. A (1)H NMR study has shown that the tripodal cap rigidifies the whole edifice, preventing ring inversion and constraining the calixarene core in a straight cone conformation.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
</country>
<region><li>Haute-Normandie</li>
<li>Région Normandie</li>
</region>
<settlement><li>Le Havre</li>
</settlement>
<orgName><li>Université du Havre</li>
</orgName>
</list>
<tree><noCountry><name sortKey="Reinaud, Olivia" sort="Reinaud, Olivia" uniqKey="Reinaud O" first="Olivia" last="Reinaud">Olivia Reinaud</name>
</noCountry>
<country name="France"><region name="Région Normandie"><name sortKey="Jabin, Ivan" sort="Jabin, Ivan" uniqKey="Jabin I" first="Ivan" last="Jabin">Ivan Jabin</name>
</region>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/France/explor/LeHavreV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001452 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001452 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/France
   |area=    LeHavreV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     pubmed:12713340
   |texte=   First C3v-symmetrical calix[6](aza)crown.
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:12713340" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a LeHavreV1

This area was generated with Dilib version V0.6.25.
Data generation: Sat Dec 3 14:37:02 2016. Site generation: Tue Mar 5 08:25:07 2024

Serveur d'exploration sur la visibilité du Havre

First C3v-symmetrical calix[6](aza)crown.

First C3v-symmetrical calix[6](aza)crown.

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur la visibilité du Havre
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.